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Self-assembly monolayer of anatase titanium oxide from solution process on indium tin oxide glass substrate for polymer photovoltaic cells

Identifieur interne : 001311 ( Chine/Analysis ); précédent : 001310; suivant : 001312

Self-assembly monolayer of anatase titanium oxide from solution process on indium tin oxide glass substrate for polymer photovoltaic cells

Auteurs : RBID : Pascal:07-0334053

Descripteurs français

English descriptors

Abstract

Titanium dioxide (TiO2) thin films were deposited on indium tin oxide (ITO) coated glass substrates by a liquid phase deposition method using two different precursor concentrations of 0.01 M and 0.005 M [NH4]2TiF6. Characterizations of the deposited TiO2 films were performed by using different spectroscopic techniques including X-ray photoelectron spectroscopy, Raman spectroscopy and X-ray diffraction. From scanning electron microscopy observation, the surface of the TiO2 films show a ricelike morphology. We have fabricated polymer-based photovoltaic cells (PCs) using the studied TiO2 films and compared their performances to those using bare ITO-coated glass substrates. The structure of the PCs is glass/ITO/Ti02/PCBM:P3HT/Au where PCBM:P3HT is poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester. The power conversion efficiency of these devices is determined to be 0.85%, which is higher than that of similar devices without TiO2 films (0.13%).

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Pascal:07-0334053

Le document en format XML

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<title xml:lang="en" level="a">Self-assembly monolayer of anatase titanium oxide from solution process on indium tin oxide glass substrate for polymer photovoltaic cells</title>
<author>
<name sortKey="Huang, Chun Hao" uniqKey="Huang C">Chun-Hao Huang</name>
<affiliation wicri:level="3">
<inist:fA14 i1="01">
<s1>Laboratoire de Physique des Matériaux et Nanostructues, Institut des Matériaux Jean Rouxel, 2 rue de la Houssinière, BP32229</s1>
<s2>44322 Nantes</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>France</country>
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<settlement type="city">Nantes</settlement>
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<s1>Department of Applied Chemistry, National Chiao Tung University</s1>
<s2>Hsinchu 30010, Taiwan</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Hsinchu 30010, Taiwan</wicri:noRegion>
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<author>
<name sortKey="Huang, Chia Hua" uniqKey="Huang C">Chia-Hua Huang</name>
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<s1>Department of Electrical Engineering, National Dong Hwa University</s1>
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<author>
<name sortKey="Nguyen, Thien Phap" uniqKey="Nguyen T">Thien-Phap Nguyen</name>
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<s1>Laboratoire de Physique des Matériaux et Nanostructues, Institut des Matériaux Jean Rouxel, 2 rue de la Houssinière, BP32229</s1>
<s2>44322 Nantes</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>France</country>
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<region type="region" nuts="2">Pays de la Loire</region>
<settlement type="city">Nantes</settlement>
</placeName>
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<author>
<name sortKey="Hsu, Chain Shu" uniqKey="Hsu C">Chain-Shu Hsu</name>
<affiliation wicri:level="1">
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<s1>Department of Applied Chemistry, National Chiao Tung University</s1>
<s2>Hsinchu 30010, Taiwan</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
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<country>République populaire de Chine</country>
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<seriesStmt>
<idno type="ISSN">0040-6090</idno>
<title level="j" type="abbreviated">Thin solid films</title>
<title level="j" type="main">Thin solid films</title>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Anatase</term>
<term>Esters</term>
<term>Glass</term>
<term>Gold</term>
<term>Indium oxides</term>
<term>Inorganic compounds</term>
<term>Liquid phase deposition</term>
<term>Monolayers</term>
<term>Organic compounds</term>
<term>Polymers</term>
<term>Precursor</term>
<term>Raman spectroscopy</term>
<term>Scanning electron microscopy</term>
<term>Self-assembly</term>
<term>Thin films</term>
<term>Tin oxides</term>
<term>Titanium oxides</term>
<term>Transition element compounds</term>
<term>Transition elements</term>
<term>X-ray photoelectron spectra</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Autoassemblage</term>
<term>Couche monomoléculaire</term>
<term>Anatase</term>
<term>Polymère</term>
<term>Couche mince</term>
<term>Dépôt phase liquide</term>
<term>Précurseur</term>
<term>Spectre photoélectron RX</term>
<term>Spectrométrie Raman</term>
<term>Diffraction RX</term>
<term>Microscopie électronique balayage</term>
<term>Verre</term>
<term>Ester</term>
<term>Composé minéral</term>
<term>Titane oxyde</term>
<term>Indium oxyde</term>
<term>Etain oxyde</term>
<term>Or</term>
<term>Métal transition composé</term>
<term>Composé organique</term>
<term>Métal transition</term>
<term>TiO2</term>
<term>Substrat verre</term>
<term>Substrat InSnO</term>
<term>Thiophène polymère</term>
<term>8116D</term>
<term>8115L</term>
<term>6110N</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr">
<term>Polymère</term>
<term>Verre</term>
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<front>
<div type="abstract" xml:lang="en">Titanium dioxide (TiO
<sub>2</sub>
) thin films were deposited on indium tin oxide (ITO) coated glass substrates by a liquid phase deposition method using two different precursor concentrations of 0.01 M and 0.005 M [NH
<sub>4</sub>
]
<sub>2</sub>
TiF
<sub>6</sub>
. Characterizations of the deposited TiO
<sub>2</sub>
films were performed by using different spectroscopic techniques including X-ray photoelectron spectroscopy, Raman spectroscopy and X-ray diffraction. From scanning electron microscopy observation, the surface of the TiO
<sub>2</sub>
films show a ricelike morphology. We have fabricated polymer-based photovoltaic cells (PCs) using the studied TiO
<sub>2</sub>
films and compared their performances to those using bare ITO-coated glass substrates. The structure of the PCs is glass/ITO/Ti02/PCBM:P3HT/Au where PCBM:P3HT is poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester. The power conversion efficiency of these devices is determined to be 0.85%, which is higher than that of similar devices without TiO
<sub>2</sub>
films (0.13%).</div>
</front>
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<fC01 i1="01" l="ENG">
<s0>Titanium dioxide (TiO
<sub>2</sub>
) thin films were deposited on indium tin oxide (ITO) coated glass substrates by a liquid phase deposition method using two different precursor concentrations of 0.01 M and 0.005 M [NH
<sub>4</sub>
]
<sub>2</sub>
TiF
<sub>6</sub>
. Characterizations of the deposited TiO
<sub>2</sub>
films were performed by using different spectroscopic techniques including X-ray photoelectron spectroscopy, Raman spectroscopy and X-ray diffraction. From scanning electron microscopy observation, the surface of the TiO
<sub>2</sub>
films show a ricelike morphology. We have fabricated polymer-based photovoltaic cells (PCs) using the studied TiO
<sub>2</sub>
films and compared their performances to those using bare ITO-coated glass substrates. The structure of the PCs is glass/ITO/Ti02/PCBM:P3HT/Au where PCBM:P3HT is poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester. The power conversion efficiency of these devices is determined to be 0.85%, which is higher than that of similar devices without TiO
<sub>2</sub>
films (0.13%).</s0>
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<s0>Autoassemblage</s0>
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<s5>01</s5>
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<s5>02</s5>
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<s5>03</s5>
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<s0>Anatase</s0>
<s5>03</s5>
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<s0>Anatasa</s0>
<s5>03</s5>
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<s0>Polymère</s0>
<s5>04</s5>
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<s0>Polymers</s0>
<s5>04</s5>
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<s0>Couche mince</s0>
<s5>05</s5>
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<s0>Thin films</s0>
<s5>05</s5>
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<s0>Dépôt phase liquide</s0>
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<s0>Précurseur</s0>
<s5>07</s5>
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<s0>Precursor</s0>
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<s5>09</s5>
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<s5>11</s5>
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<s0>Scanning electron microscopy</s0>
<s5>11</s5>
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<fC03 i1="12" i2="3" l="FRE">
<s0>Verre</s0>
<s5>12</s5>
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<s0>Glass</s0>
<s5>12</s5>
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<s0>Ester</s0>
<s5>13</s5>
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<s0>Esters</s0>
<s5>13</s5>
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<s0>Composé minéral</s0>
<s5>14</s5>
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<s0>Inorganic compounds</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Titane oxyde</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG">
<s0>Titanium oxides</s0>
<s2>NK</s2>
<s5>15</s5>
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<fC03 i1="16" i2="3" l="FRE">
<s0>Indium oxyde</s0>
<s2>NK</s2>
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<s0>Indium oxides</s0>
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<s2>NK</s2>
<s5>17</s5>
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<s0>Tin oxides</s0>
<s2>NK</s2>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Or</s0>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG">
<s0>Gold</s0>
<s2>NC</s2>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>Métal transition composé</s0>
<s5>29</s5>
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<s0>Transition element compounds</s0>
<s5>29</s5>
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<s5>30</s5>
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<s5>30</s5>
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<s5>31</s5>
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<s4>INC</s4>
<s5>47</s5>
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<s0>Substrat InSnO</s0>
<s4>INC</s4>
<s5>48</s5>
</fC03>
<fC03 i1="25" i2="3" l="FRE">
<s0>Thiophène polymère</s0>
<s4>INC</s4>
<s5>49</s5>
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<fC03 i1="26" i2="3" l="FRE">
<s0>8116D</s0>
<s4>INC</s4>
<s5>71</s5>
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<fC03 i1="27" i2="3" l="FRE">
<s0>8115L</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fC03 i1="28" i2="3" l="FRE">
<s0>6110N</s0>
<s4>INC</s4>
<s5>73</s5>
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<fN21>
<s1>218</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>EMRS 2006 Conference, Symposium J: Synthesis Processing and Characterization of Nanoscale Functional Oxide Films</s1>
<s3>Nice FRA</s3>
<s4>2006-05-29</s4>
</fA30>
</pR>
</standard>
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